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- W860818983 abstract "We report the first UV laser action spectra of mass-selected aggregates composed of the cationic and anionic constituents of two ionic liquids, i.e. [BMIM+]n[Tf2N−]m and [EMIM+]n[Tf2N−]m where n ≠ m and n, m = 1,2. Each aggregate cluster displays a maximum absorption at 220 nm, the high energy limit scanned. However, the anionic and cationic aggregate photofragmentation cross-sections are notably different, indicating distinctive decay mechanisms. We compare our spectra to other gas-phase spectroscopic methods and discuss the general utility of our technique as a facile route to obtaining gas-phase electronic spectra of isolated ionic liquids." @default.
- W860818983 created "2016-06-24" @default.
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- W860818983 date "2015-08-01" @default.
- W860818983 modified "2023-10-15" @default.
- W860818983 title "UV laser spectroscopy of mass-selected ionic liquid building blocks in the gas-phase" @default.
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- W860818983 doi "https://doi.org/10.1016/j.cplett.2015.06.023" @default.
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