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- W86102441 abstract "The rate of heteroexchange of oxygen of the electrolyte 0.906ZrO/sub 2/ + 0.094Sc/sub 2/O/sub 3/ in an atmosphere of free oxygen at the temperature 700-850/sup 0/C and oxygen pressure 10-40 mm Hg was measured by the method of isotopic exchange of oxygen using the isotope /sup 18/O. The rate of homoexchange of oxygen, the activation energies of the reactions of homo- and heteroexchange, the values of the orders of the dependence of the rates of these reactions on the oxygen pressure, as well as the contributions of various types of exchange to the total rate, were calculated. The characteristics of exchange obtained were compared with those for an electrolyte with composition 0.9ZrO/sub 2/ + 0.1Y/sub 2/O/sub 3/. Reversible dissociative adsorption and desorption of oxygen is suggested as the limiting steps of heteroexchange." @default.
- W86102441 created "2016-06-24" @default.
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- W86102441 date "1983-02-01" @default.
- W86102441 modified "2023-09-27" @default.
- W86102441 title "Isotopic exchange between the oxygen of a solid oxide electrolyte based on ZrO/sub 2/ and gaseous oxygen" @default.
- W86102441 hasPublicationYear "1983" @default.
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