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- W862501831 abstract "The complex formation of Hg 2 + ion with five recently synthesized benzo-substituted macrocyclic diamides in binary nitromethane + dimethylformamide mixtures was studied by differential pulse polarography at 25°C. The stoichiometry and stability of the complexes were determined by monitoring the shift in the Hg 2 + differential pulse peak potential against the macrocycles concentration. In all cases studied, it was found that the stability of the resulting 1:1 complex decreases drastically by increasing the amount of dimethylformamide in the binary mixtures. The observed stability order in a given solvent mixture is discussed in terms of the cavity size, structural flexibility and nature of the substituted on the macrocyclic diamide ring." @default.
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- W862501831 date "2002-12-12" @default.
- W862501831 modified "2023-09-24" @default.
- W862501831 title "Differential Pulse Polarographic Study of Mercury Complexes with Some Benzo-Substituted Macrocyclic Diamides In Binary Nitromethane + Dimethylformamide Mixtures" @default.
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