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- W862876797 abstract "As one of the most important catalysts in polyethylene industry,Phillips catalyst(CrO_x/SiO_2)was quite unique for its activation by ethylene monomer without using any activator like alkyl-aluminium or MAO.In this work,the density functional theory(DFT)calculation combined with paired interacting orbitals(PIO)method was applied for the theoretical studies on coordination reaction mechanism between ethylene monomer and two model catalysts namely Cr(Ⅱ)(OH)_2(M1) and silsesquioxane-supported Cr(Ⅱ)(M2)as sur..." @default.
- W862876797 created "2016-06-24" @default.
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- W862876797 date "2008-01-01" @default.
- W862876797 modified "2023-09-23" @default.
- W862876797 title "SIMULATION MODELING ON THE COORDINATION MECHANISM OF ETHYLENE MONOMER ON VARIOUS PREREDUCED Cr(II)O_x/SiO_2 PHILLIPS POLYETHYLENE MODEL CATALYSTS" @default.
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