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- W864338093 abstract "Process B in Eq. (3) has no precedent for 1 to our knowledge. Recently, Yasuda and coworker suggested the possible carbocation formation from the radical cation formed in the photochemical electron transfer reaction of phosphonation. The formation of neutral phosphoranyl radicals by combination of ions has received little attention, especially under chemical oxidation conditions. Evidence for the competition between steps A and B in Eq. (3) can be explained by the product ratio obtained from one electron oxidation of a series of ROP(OEt)2 in CH2Cl2. The tris(p-bromophenyl)aminium hexachloroantimonate, (p-BrC6H4)3NSbCl6 (7 • ) served as an oxidant. A weighed amount of phosphite, ROP(OEt)2, was added via a septum to 25 mL of an argon flushed 0.01 M CH2Cl2 solution of 7 • +" @default.
- W864338093 created "2016-06-24" @default.
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- W864338093 date "1997-01-01" @default.
- W864338093 modified "2023-09-27" @default.
- W864338093 title "The Reaction of Alkylphosphite with Tris( p-bromophenyl)aminium hexachloroantimonate: An Efficient Chemical One Electron Oxidation for the Carbocation Formation" @default.
- W864338093 hasPublicationYear "1997" @default.
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