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- W869069849 abstract "Two triangular tripalladium compounds, [Pd3(μ3-Cl)2(HqnS)6]Cl2 (1) (HqnS = quinoline–2(1H)–thione), and [Pd3(μ3-Cl)2(Et2dtc)2(PPh3)2]·C6H6 (2) (Et2dtc = N, N′-diethyldithiocarbamate anion), were prepared. Their single crystal X-ray structure analyses revealed they have a similar trigonal bipyramidal framework of Pd3(μ3-Cl)2 with two chlorine atoms in apical positions. Each Pd atom in all clusters has two additional coordination sites to establish a square planar cis-PdL2(μ3-Cl)2 geometry. In compound 1, six sulfur atoms of six HqnS ligands with thion form are coordinated to the vacant sites of the Pd3(μ3-Cl)2 core. Two coordination sites of one of the three Pd atoms in 2 are occupied by two triphenylphosphines and those of the other two are coordinated by two S atoms of Et2dtc. Although both compounds have 50 valence electrons, only 1 shows paramagnetic behavior. Crystallographic data are as follows. 1: Pd3Cl4S6N6C54H42, triclinic, P1- a = 14.988(5), b = 17.328(3), c = 12.642(1) A, α = 93.61(1), β = 96.06..." @default.
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- W869069849 title "Syntheses, Structures, and Magnetic Properties of Di-<b><i>μ</i></b><sub>3</sub>-Chloride-Bridged Tripalladium Compounds, [Pd<sub>3</sub>(<b><i>μ</i></b><sub>3</sub>-Cl)<sub>2</sub>(HqnS)<sub>6</sub>]Cl<sub>2</sub>(HqnS = Quinoline–2(1<b><i>H</i></b>)–thione) and [Pd<sub>3</sub>(<b><i>μ</i></b><sub>3</sub>-Cl)<sub>2</sub>(Et<sub>2</sub>dtc)<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>]·C<sub>6</sub>H<sub>6</sub>(Et<sub>2</sub>dtc =<b><i>N</i></b>,<b><i>N</i></b><sup>′</sup>–Diethyldithiocarbamate)" @default.
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- W869069849 doi "https://doi.org/10.1246/bcsj.73.651" @default.
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