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- W87085208 abstract "An analysis of 15 bands of the [Formula: see text] system of D 2 O + is given. All assigned lines are tabulated. The rotational structures of the [Formula: see text], 1, and 3 levels of the ground state are fitted to the Watson asymmetric rotor Hamiltonian with added spin-rotation terms. For the upper state, the rotational structures of various substates are expressed: for [Formula: see text], in terms of a simple formula for linear molecules; and for [Formula: see text], 2, and 3, in terms of a modified Hill – Van Vleck formula given by Jungen, Hallin, and Merer. From the rotational constants of the ground state, term values are calculated and a small portion of a Type-B infrared band is derived. Some predicted microwave lines are also given. The bond length and bond angle of the molecule in the ground state (ν = 0) are r 0 = 0.9987 ± 0.0002 Å and θ 0 = 110.17 ± 0.02 deg." @default.
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- W87085208 date "1987-07-01" @default.
- W87085208 modified "2023-10-17" @default.
- W87085208 title "Electronic spectrum of D<sub>2</sub>O<sup>+</sup>" @default.
- W87085208 doi "https://doi.org/10.1139/p87-108" @default.
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