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• W873086329 abstract "Volatile organic compounds (VOCs) which are released into atmosphere from various sources are very harmful to the environment and human health. Tetrachloroethylene (PCE) and trichloroethylene (TCE) belong to the most toxic group of VOCs and their emission are strictly regulated. Different technologies have been studied to remove VOCs from gas phase. Electron beam (EB) treatment is one of the most promising technologies for the removal of low concentration VOCs contained in air. One of the EB technology advantages is an energy saving process [8, 9]. TCE decomposition in air by using this technology has been extensively studied [4, 12−14]. This paper is devoted to the theoretical modeling of the kinetics of HClC=CCl2 (TCE) decomposition during electron beam irradiation in dry and humid air, respectively. Computer calculation based on a theoretical model was performed using the published experimental results. The experimental data of HClC=CCl2 decomposition in dry air under the influence of electron beam were reported by Vitale et al. for temperature 25°C, pressure 1 atm, dose D < 30 kGy, dose rate ≥ 100 kGy/s [13]. Similar experiments for humid air (200–1000 ppm H2O) were performed by Hakoda et al. [4] for the same temperature and pressure, dose level D < 40 kGy and dose rate 2.1 kGy/s. Comparing the experimental results of HClC=CCl2 decomposition under the influence of electron beam in dry air [13] with that in humid air [4], we find that the dose which is needed to obtain 90% of HClC=CCl2 decomposition in humid air is always significantly lower than that in dry air for the same level of the initial concentration of TCE. This indicates Theoretical study of dose and dose rate effect on trichloroethylene (HClC=CCl2) decomposition in dry and humid air under electron beam irradiation Henrieta Nichipor, Svetlana Yacko, Yongxia Sun, Andrzej G. Chmielewski, Zbigniew Zimek" @default.
• W873086329 created "2016-06-24" @default.
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• W873086329 date "2008-01-01" @default.
• W873086329 modified "2023-09-23" @default.
• W873086329 title "Theoretical study of dose and dose rate effect on trichloroethylene (HClC=CCl2) decomposition in dry and humid air under electron beam irradiation" @default.
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