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- W873166640 abstract "New PVC plasticizer, 2,2,4-trimethyl-1,3-pentanediol-1-butyrate-3- isobutyrate was synthesized via simple esterification with butyric acid and Texanol(a trademark of Eastman Chemicals), the mixture of 2,2,4-trimethyl-1,3-pentanediol-3- isobutyrate and 2,2,4-trimethyl-1,3-pentanediol-1-isobutyrate. The analysis of 1 H-1D, 13 C-1D NMR and HMBC spectra identified internal-ester-transfer of 2,2,4-trimethyl- 1,3-pentanediol-1-isobutyrate during the reaction. 2,2,4-trimethyl-1,3-pentanediol-1- butyrate-3-isobutyrate gave better properties in PVC than 2,2,4-trimethyl-1,3- pentanediol diisobutyrate(TXIB, a trademark of Eastman Chemicals) such as lower viscosity, higher tensile strength and better elongation. In particular, remarkably reduced migration compared with TXIB suggested a reduced emission of VOC(volatile organic compound) from PVC. Keyword : PVC plasticizer, NMR, HMBC, VOC(volatile organic compound)" @default.
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- W873166640 date "2005-01-01" @default.
- W873166640 modified "2023-09-23" @default.
- W873166640 title "The synthesis and the structural analysis of advanced PVC plasticizer, 2,2,4-trimethyl-1,3-pentanediol-1-butyrate-3-isobutyrate" @default.
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