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- W87354097 abstract "This chapter describes supercritical carbon dioxide as a solvent for organic compounds present in aqueous salt solutions. The phase equilibrium of the ternary system carbon dioxide + water + acetic acid and the quaternary systems carbon dioxide + water + acetic acid + (sodium chloride or sodium acetate) was investigated experimentally for temperatures between 313 and 353 K at pressure up to 16 MPa. These measurements were performed with the help of an apparatus realizing the continuous flow technique. The main focus of the experimental investigation was on the effects of the salts on the composition of the coexisting phases. The experimental results revealed that the concentration of the carbon dioxide in the aqueous phase decreases in the presence of both sodium chloride and sodium acetate. Both salts reveal different effects on the concentration of acetic acid in the aqueous phase. The presence of sodium chloride reduces the concentration of acetic acid in the aqueous phase whereas sodium acetate causes an increase in the concentration of acetic acid in the aqueous phase. The experimental results are described by an extension of the Peng–Robinson equation of state. In addition, the chapter describes the properties of the salt-free mixtures." @default.
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- W87354097 date "2004-01-01" @default.
- W87354097 modified "2023-09-24" @default.
- W87354097 title "Supercritical carbon dioxide as solvent for organic compounds present in aqueous salt solutions" @default.
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- W87354097 doi "https://doi.org/10.1016/b978-044451574-2/50007-9" @default.
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