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- W87816156 abstract "We have examined the effects of viscosity on the rate of photosensitization of diaryliodonium salts by anthracene. Fluorescence spectroscopy was used to monitor the photosensitization reaction in propanol/glycerol solutions of differing viscosities. As the viscosity was increased, the rate of photosensitization decreased in a manner qualitatively described by the Smoluchowski-Stokes-Einstein equation for bimolecular elementary reactions, coupled with numerical solution of the photophysical equations. Based on these studies, we would expect the viscosity change during polymerization to have a profound effect on the rate of photosensitization due to a marked decrease in the rates of the diffusion-controlled bimolecular reactions. Therefore, the rate of photosensitization may become extremely low after a certain degree of polymerization with further reaction arising primarily from propagation of existing active centers." @default.
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- W87816156 date "1997-11-01" @default.
- W87816156 modified "2023-10-14" @default.
- W87816156 title "Effect of Viscosity on the Rate of Photosensitization of Diaryliodonium Salts by Anthracene" @default.
- W87816156 doi "https://doi.org/10.1021/bk-1997-0673.ch008" @default.
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