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• W878290758 abstract "Abstract In this work, Stark effect measurements have been carried out on several transitions C-13 substituted species of triply-deuterated (D3) methanol. The analysis of the data allowed the determination of the dipole moment components in the first two torsional states of the ground vibrational state of this species. The extrapolated zero field frequencies of the transitions studied have been determined and found to be in excellent agreement with known values. For the torsional ground state the values {in Debye (D)} of μa = 0.9080(9) and μb = 1.4378(10) have been obtained for this species. These values increase for the first excited state as was observed for other species. The dipole moment values are considerably higher than the non-deuterated species. To our knowledge the present study represents the measurement of the most accurate dipole moment values of 13CD3OH for the first time. The results obtained will prove useful for radio astronomy and in understanding of large amplitude internal energy pathways in polyatomic molecules." @default.
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• W878290758 date "2015-10-01" @default.
• W878290758 modified "2023-09-27" @default.
• W878290758 title "Dipole moment of methanol by microwave stark spectroscopy IV: 13CD316OH species" @default.
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• W878290758 doi "https://doi.org/10.1016/j.molstruc.2015.05.042" @default.
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