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- W88291505 abstract "The microwave spectrum of methylphosphonic difluoride, CH3POF2, has been reinvestigated from 18.5 to 40.0 GHz. Both a-type and b-type transitions were observed and R-branch assignments have been made for the ground vibrational state. The determined rotational constants were found to be: A = 4495.91 ± 0.04, B = 4271.86 ± 0.03 and C = 4125.90 ± 0.03 MHz. A diagnostic least squares adjustment of the heavy atom structural parameters yielded the following bond lengths and angles: r(P-C) = 1.795 ± 0.019 Å, r(P-F) = 1.544 ± 0.011 Å, r(PO) = 1.442 ± 0.009 Å, ∠FPF = 99.2 ± 1.0°, ∠FPC = 100.5 ± 2.3°, and ∠CPO = 118.2 ± 1.5°. The values of the dipole moment components were determined from the Stark effect to be: ¦μa¦ = 3.50 ± 0.25, ¦μb¦ = 1.15 ± 0.07, ¦μc¦ = 0.0 and ¦μt¦ = 3.69 ± 0.26 D. These results are compared to corresponding quantities for similar molecules." @default.
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- W88291505 date "1982-02-01" @default.
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- W88291505 title "Spectra and structure of organophosphorus compounds" @default.
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- W88291505 doi "https://doi.org/10.1016/0022-2860(82)80010-0" @default.
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