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- W883674596 abstract "The results of the analysis of thermal stability for zinc (II) and boron (III) complexes with 3,3′,5,5′-tetramethyl-4-ethyl-4′-iodo-2,2-dipyrrin [HL1], 3,3′-diamyl-4,4′-dimethyl-5,5′-dibromo-2,2′-dipyrrin [HL2] and 3,3′,5,5′-tetramethyl-4,4′-dibromo-2,2′-dipyrrin [HL3] of the composition [Zn(L1)2]–[Zn(L3)2] and [BF2L1]–[BF2L3] are presented. The influence of halogenation of dipyrrin ligand is manifested in decreasing thermal stability of [Zn(L)2] and [BF2L] when replacing 4,4′-dibromosubstituted dipyrrin on 5,5′-dibromo- or 4-monoiodosubstituted ligand. Intramolecular red-ox-reactions with participation of halogen atoms are the main cause of thermal stability lowering of dipyrrinates [Zn(L)2] and [BF2L] compared with alkylsubstituted analogs. The obtained results are interesting for the development of laser dyes and sensors for PDT." @default.
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- W883674596 date "2015-08-01" @default.
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- W883674596 title "Influence of structural factors on the thermal stability of zinc(II) and boron(III) complexes with iodo- and bromosubstituted 2,2′-dipyrrines" @default.
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- W883674596 doi "https://doi.org/10.1016/j.tca.2015.05.028" @default.
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