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• W887938580 abstract "The enantioselective synthesis of 4-epi-fagomine was accomplished starting from dioxanone and Cbz-protected benyzlamine, in 4 steps, with 18% overall yield. The key feature of this synthetic approach is the tactical combination of reactions: organocatalyzed aldolization/reductive amination, which allows for a quick formation of heterocyclic rings with defined absolute configuration of all stereogenic centers. Two hydroxypipecolic acids and a reduced fagomine analogue were also synthesized." @default.
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• W887938580 date "2015-09-01" @default.
• W887938580 modified "2023-10-15" @default.
• W887938580 title "Organocatalyzed synthesis of (−)-4-epi-fagomine and the corresponding pipecolic acids" @default.
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• W887938580 doi "https://doi.org/10.1016/j.tet.2015.07.036" @default.
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