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- W89024118 abstract "Abstract Stereoselective synthesis of polycycles on the basis of the new generation of α-alkyl-o-quinodimethanes and o-quinone methide N-alkylimines by the fluoride anion induced 1,4-elimination of o-[α-(trimethylsilyl)-alkyl]benzyltrimethylammonium halides and o-[N-(trimethylsilyl)-N-alkyl-amino]benzyltrimethylammonium halides is described. Cycloaddition reactions of α-alkyl-α′-[2-( N , N -dimethylamino)alkoxy]-o-quinodimethanes having an asymmetric center in the α′-alkoxy substituent, which are generated from the 1,4-elimination of 2-[o-[1-(trimethylsilyl)alkyl]phenyl]-3,3-dimethyloxazolidinium salts, may provide a new approach to asymmetric synthesis of polycycles." @default.
- W89024118 created "2016-06-24" @default.
- W89024118 creator A5034939239 @default.
- W89024118 date "1983-01-01" @default.
- W89024118 modified "2023-09-24" @default.
- W89024118 title "A NEW METHODOLOGY FOR THE GENERATION OF o-QUINODIMETHANES AND RELATED INTERMEDIATES — AN APPROACH TO ASYMMETRIC SYNTHESIS OF POLYCYCLES" @default.
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- W89024118 doi "https://doi.org/10.1016/b978-0-08-029217-5.50018-8" @default.
- W89024118 hasPublicationYear "1983" @default.
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