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- W89079506 abstract "Kinetics of oxidn. of psychotropic drugs, chlorpromazine hydrochloride (CPH) and fluphenazine dihydrochloride (FPH) by sodium N-chlorobenzenesulfonamide (CAB) at pH 1.6, was studied spectrophotometrically by measuring I»max at 570 nm (for CPH) and 530 nm (for FPH). The reaction rate shows a first-order dependence for [CAB] and [substrates] and an inverse fractional-order for [H+]. Addn. of halide ions and benzenesulfonamide (the redn. product of CAB) or the variation in ionic strength and dielec. const. of the buffer medium showed no significant effect on the reaction rate. The reaction was studied at different temp. and activation parameters were evaluated. Proposed general mechanism and the derived rate law/s are consistent with the obsd. kinetics. [on SciFinder(R)]" @default.
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- W89079506 date "2002-06-01" @default.
- W89079506 modified "2023-09-24" @default.
- W89079506 title "Oxidation of psychotropic drugs by sodium N-chlorobenzenesulphonamide: A kinetic and mechanistic study." @default.
- W89079506 hasPublicationYear "2002" @default.
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