Matches in SemOpenAlex for { <https://semopenalex.org/work/W894465986> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W894465986 endingPage "748" @default.
- W894465986 startingPage "743" @default.
- W894465986 abstract "Photochemical reactions of saccharin with tertiary amines were explored. Saccharin was found to undergo an acid-base reaction with N-trimethylsilylmethyl-N,N-diethyl amine to form N-trimethylsilylmethyl-N,N-diethyl ammonium saccharin salt which is in equilibrium with free saccharin and N-trimethylsilylmethyl-N,N-diethyl amine insolution. Photoreaction of N-trimethylsilylmethyl-N,N-diethyl ammonium saccharin in results in the generation of desilylmethylated product, N,N-diethyl ammonium saccharin mainly along with benzamide. Photoreaction of N-methylsaccharin with N-trimethylsilylmethyl-N,N-diethyl amine in leads to the production of o-(N-methylcarbamoyl)-N-ethylbenzenesulfonamid e as the major product along with N-methylbenzamide as the minor product. On the other hand, photoreaction of N,N,N-triethyl ammonium saccharin, generated from saccharin and triethylamine, produces N-methylbenzamide as the exclusive product. These photoreactions are quenched by oxygen indicating that triplets of saccharin and N-methylsaccharin are the reactive excited states. Based on the consideration of the redox potentials of saccharin and N-trimethylsilylmethyl-N,N-diethyl amine, and the nature of photoproducts, pathways involving initial triplet state single electron transfer are proposed for photoreactions of the saccharins with the -silylamine." @default.
- W894465986 created "2016-06-24" @default.
- W894465986 creator A5003586604 @default.
- W894465986 creator A5057395176 @default.
- W894465986 creator A5060966196 @default.
- W894465986 creator A5066549957 @default.
- W894465986 creator A5073608676 @default.
- W894465986 creator A5082517879 @default.
- W894465986 creator A5091134003 @default.
- W894465986 date "1994-01-01" @default.
- W894465986 modified "2023-09-23" @default.
- W894465986 title "Photochemical Reactions of Saccharin-$alpha$-Silylamine Systems. Desilylmethylation of $alpha$-Silylamine via Single Electron Transfer Pathway" @default.
- W894465986 hasPublicationYear "1994" @default.
- W894465986 type Work @default.
- W894465986 sameAs 894465986 @default.
- W894465986 citedByCount "0" @default.
- W894465986 crossrefType "journal-article" @default.
- W894465986 hasAuthorship W894465986A5003586604 @default.
- W894465986 hasAuthorship W894465986A5057395176 @default.
- W894465986 hasAuthorship W894465986A5060966196 @default.
- W894465986 hasAuthorship W894465986A5066549957 @default.
- W894465986 hasAuthorship W894465986A5073608676 @default.
- W894465986 hasAuthorship W894465986A5082517879 @default.
- W894465986 hasAuthorship W894465986A5091134003 @default.
- W894465986 hasConcept C123669783 @default.
- W894465986 hasConcept C131779359 @default.
- W894465986 hasConcept C134018914 @default.
- W894465986 hasConcept C155647269 @default.
- W894465986 hasConcept C178790620 @default.
- W894465986 hasConcept C185592680 @default.
- W894465986 hasConcept C2779147919 @default.
- W894465986 hasConcept C2779870022 @default.
- W894465986 hasConcept C2781283055 @default.
- W894465986 hasConcept C3018358672 @default.
- W894465986 hasConcept C71924100 @default.
- W894465986 hasConcept C75473681 @default.
- W894465986 hasConceptScore W894465986C123669783 @default.
- W894465986 hasConceptScore W894465986C131779359 @default.
- W894465986 hasConceptScore W894465986C134018914 @default.
- W894465986 hasConceptScore W894465986C155647269 @default.
- W894465986 hasConceptScore W894465986C178790620 @default.
- W894465986 hasConceptScore W894465986C185592680 @default.
- W894465986 hasConceptScore W894465986C2779147919 @default.
- W894465986 hasConceptScore W894465986C2779870022 @default.
- W894465986 hasConceptScore W894465986C2781283055 @default.
- W894465986 hasConceptScore W894465986C3018358672 @default.
- W894465986 hasConceptScore W894465986C71924100 @default.
- W894465986 hasConceptScore W894465986C75473681 @default.
- W894465986 hasIssue "9" @default.
- W894465986 hasLocation W8944659861 @default.
- W894465986 hasOpenAccess W894465986 @default.
- W894465986 hasPrimaryLocation W8944659861 @default.
- W894465986 hasRelatedWork W1574403361 @default.
- W894465986 hasRelatedWork W1999364210 @default.
- W894465986 hasRelatedWork W2011276472 @default.
- W894465986 hasRelatedWork W2014059458 @default.
- W894465986 hasRelatedWork W2016248629 @default.
- W894465986 hasRelatedWork W2023642524 @default.
- W894465986 hasRelatedWork W2024301210 @default.
- W894465986 hasRelatedWork W2030633489 @default.
- W894465986 hasRelatedWork W2036687911 @default.
- W894465986 hasRelatedWork W2050876983 @default.
- W894465986 hasRelatedWork W2063602851 @default.
- W894465986 hasRelatedWork W2078552969 @default.
- W894465986 hasRelatedWork W2161643603 @default.
- W894465986 hasRelatedWork W2284106921 @default.
- W894465986 hasRelatedWork W2333669766 @default.
- W894465986 hasRelatedWork W2526499283 @default.
- W894465986 hasRelatedWork W2565303083 @default.
- W894465986 hasRelatedWork W2599664041 @default.
- W894465986 hasRelatedWork W2949991479 @default.
- W894465986 hasRelatedWork W2952165482 @default.
- W894465986 hasVolume "15" @default.
- W894465986 isParatext "false" @default.
- W894465986 isRetracted "false" @default.
- W894465986 magId "894465986" @default.
- W894465986 workType "article" @default.