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- W899761323 abstract "The stability constants of the Co(II), Ni(II), Cu(II) and Zn(II) complexes with 2-benzoylpyridine 4-phenyl-3-thiosemicarbazone were determined using a spectrophotometric method at different temperatures (25, 30, 35 and 40 ± 0.1◦C) and ionic strengths (0.05, 0.01 and 0.20 M KNO3 ) in 50 % (v/v) aqueous ethanol. Plots of thermodynamic stability constants at zero ionic strength (ln K◦ ) versus T−1 gave linear curves and ∆ H◦ and ∆ S◦ were also calculated from these plots. Moreover, the changes in free energy for each metal-ligand system were calculated from the following equation. ∆ G◦ = -RT ln K◦" @default.
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- W899761323 date "1998-06-05" @default.
- W899761323 modified "2023-09-26" @default.
- W899761323 title "Thermodynamic Studies of Some Complexes of 2-benzoylpyridine 4-phenyl-3-thiosemicarbazone" @default.
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