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• W90044761 abstract "This chapter focuses on thermodynamics and kinetics of the intramolecular complex in flavin-adenine dinucleotide (FAD). The existence of an intramolecular complex in FAD between adenine and isoalloxazine rings is now well proven. The quantum efficiency of a population of fluorescent molecules can be affected by static quenching due to molecular interactions in the ground state predating excitation and dynamic quenching of the excited singlet state because of interactions throughout the excited singlet lifetime. A visual comparison of the measured lifetimes and quantum efficiencies immediately reveals the nature of the quenching. Van't Hoff and Arrhenius plots yielded the thermodynamic constants, which reveal four important characteristics of the strong isoalloxazine–adenine interactions in water. The quantitative results are in agreement with other experimental observations on stacked dinucleotides and polynucleotides in which negative entropy and enthalpy changes of formation have also been found." @default.
• W90044761 created "2016-06-24" @default.
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• W90044761 date "1972-01-01" @default.
• W90044761 modified "2023-09-23" @default.
• W90044761 title "THERMODYNAMICS AND KINETICS OF THE INTRAMOLECULAR COMPLEX IN FLAVIN-ADENINE DINUCLEOTIDE" @default.
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• W90044761 doi "https://doi.org/10.1016/b978-0-08-016874-6.50051-5" @default.
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