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- W90267890 abstract "The emission spectrum of the AsS radical, excited in a quartz tube by a 2450 MHz oscillator, was photographed on a high resolution spectrograph from 2450 to 6900 Å. Seven bands around 6000 Å showing clear rotational structures were chosen for the first rotational analysis of the AsS spectrum. The bands were found to arise from a 2 Π 3/2 – 2 Π 3/2 transition. The rotational and vibrational constants of the two states derived from the present work are consistent with the previous vibrational analysis of the A′ 2 Π 3/2 –X 2 Π 3/2 system. The constants of the upper doublet component of the ground state, X 2 Π 3/2 , are ω e = 562.40 cm −1 , ω e x e = 2.02 cm −1 , r e = 2.0216 Å; the constants of the A′ 2 Π 3/2 state are ΔG′(1/2) = 403.37 cm −1 , ν 0,0 = 18 621.21 cm −1 , r e = 2.2500 Å." @default.
- W90267890 created "2016-06-24" @default.
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- W90267890 date "1971-05-15" @default.
- W90267890 modified "2023-09-24" @default.
- W90267890 title "Spectrum of AsS. I. Analysis of the A′2Π3/2–X2Π3/2 Band System" @default.
- W90267890 doi "https://doi.org/10.1139/p71-149" @default.
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