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- W90413676 abstract "ABSTRACT Sulphur dioxide gas readily dissolves in water to give “sulphurous acid” which is an equilibrium mixture involving SO2 === HSO3- ==== SO32−. The importance of these equilibria in water pollution studies lies in the fact that metal ions in water are quite reactive towards aqueous sulphite. We have been investigating the kinetics and the mechanism of the SO2 uptake and the dissociation reactions for a series of complexes comprising the types M(L)5OH and M(L)4 (OH)2 (charges are omitted for clarity) where L4 and L5 are amine ligand groupings of various kinds and M represents either Co, Pt or Cr. The structural and kinetic data obtained are discussed with respect to their mechanistic significance and some general conclusions are drawn concerning the nucleophilicity of hydroxo metal complexes toward sulphur dioxide in aqueous systems." @default.
- W90413676 created "2016-06-24" @default.
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- W90413676 date "1988-01-01" @default.
- W90413676 modified "2023-09-26" @default.
- W90413676 title "THE IMPORTANCE OF SULPHITE EQUILIBRIA IN WATER POLLUTION: A KINETIC CONSIDERATION" @default.
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- W90413676 doi "https://doi.org/10.1016/b978-0-08-036884-9.50083-1" @default.
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