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- W908718837 abstract "新的NLO化合物Ce(MoO2)(OH)(IO3)4由水热法在170℃下制备得到.X射线单晶结构分析表明,该化合物以极性空间群P21结晶,晶体学参数为:a=0.70144(8)nm,b=1.41554(10)nm,c=0.70969(6)nm,β=115.318(7)°,V=0.6369(1)nm3,Z=2.Ce(MoO2)(OH)(IO3)4的晶体结构是由八配位的Ce3+阳离子,高度畸变的MoO66-八面体,和碘酸根阴离子基团组成的复杂三维网所构成.分析其结构表明,含有Ⅰ(3)和Ⅰ(4)的碘酸根基团的孤电子对的合成方向指向极化轴b,从而导致晶体结构具有非中心对称性.此外,红外光谱进一步证实了MoO66-,IO3-基团和Mo-OH作用的存在." @default.
- W908718837 created "2016-06-24" @default.
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- W908718837 date "2005-01-01" @default.
- W908718837 modified "2023-09-24" @default.
- W908718837 title "新的NLO化合物Ce（MoO2）（OH）（IO3）4的合成和晶体结构" @default.
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