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- W910585535 abstract "Catalytic effects of colloidal metals and semi-conductors were recognized in the early days of colloid chemistry. Many redox reactions, for example, are catalyzed by colloidal metals. Nevertheless, the mechanism of these catalytic effects is not as well understood as that of reactions in homogeneous solutions. In order to understand these effects, a research project was established at the Hahn-Meitner-Institut some 12 years ago, in which the chemical behaviour of reactive chemical species at interfaces was to be investigated. During the first years of this program a fast method was developed to measure the polarograms of short-lived free radicals (1). After considerable information about electron transfer reactions of radicals at the mercury electrode had been acquired, this compact electrode was replaced by metal colloids and the electron transfer reactions between the radicals and the colloids were studied. These studies led to the detection of the electron storing properties of certain metal colloids and of reactions of the stored electrons." @default.
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- W910585535 date "1985-01-01" @default.
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- W910585535 title "Catalysis of Chemical Reactions by Colloidal Metals and Semiconductors" @default.
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- W910585535 doi "https://doi.org/10.1007/978-3-0348-6513-5_6" @default.
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