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- W91302175 abstract "ABSTRACT A series of titanium silicalites with the MEL structure has been characterized by XPS, IR and catalytic activity in hydroxylation of n-hexane. Two Ti sites were revealed by XPS, a low and a high coordination species. Sodium impurities were found to decrease the intensity of 960 cm-1 IR band and to favor the decomposition of H2O2 at the expense of partial oxidation products. Based on the present data and previous XANES and EXAFS data, an overall picture of the active sites and the effect of sodium impurities is proposed." @default.
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- W91302175 date "1993-01-01" @default.
- W91302175 modified "2023-09-24" @default.
- W91302175 title "LOCAL ENVIRONMENT OF TITANIUM IN TITANIUM SILICALITE (TS-2)" @default.
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- W91302175 doi "https://doi.org/10.1016/b978-1-4832-8383-8.50053-2" @default.
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