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- W914070988 abstract "A novel vanadate decamer, involving all vanadium atoms present in +5 oxidation and one formhydroxamic acid dimer cation readical, has been synthesized. The single-crystal X-ray diffraction shows that the orange crystal is formed in the triclinic system, space group Pi, a=8.4960(17), b=10.447 (2), c=11. 299 (2)A, α=68.82 (3)°, β= 87.35(3)°, γ=66. 97 (3)°. V=855.3(3)A^3, Z=8, R1=0.0857, wR2=0.2551. X-ray crystallographic and packing in superlattice studies showed that the crystal structure was constructed by electrostatic attraction of O-H…O hydrogen bonds between formhydroxamic acid dimer cation and decavanadate polyanion. Formhydroxamic acid dimer is got through controlling the condition of the reaction using formhydroxamic acid." @default.
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- W914070988 date "2004-01-01" @default.
- W914070988 modified "2023-09-23" @default.
- W914070988 title "Synthesis and Crystal Structure of a Novel Compound of （C2N2H8O2） H6V10O28" @default.
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