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- W917657308 abstract "Abstract The EPR spectrum of Mn 2+ ions observed in nano-powders of wurtzite ZnO phase (ZnO Wt ) with 0.1 wt% of carbon nanoparticles subjected to mechanical processing (MP) for t MP >90 min where different than the well-known EPR spectrum of Mn 2+ in ZnO Wt . Such spectrum was observed earlier and it was attributed to either a new phase or a highly disordered nanocrystalline ZnO Wt . Spin–Hamiltonian (S–H) parameters and line width (Δ B ) have been determined by computer simulation of observed EPR spectrum of Mn 2+ : g =2.0010±0.0004, | A |=(73.6 ±0.3)·10 −4 cm −1 , | D |=(102 ±30)·10 −4 cm −1 , Δ B ≈0.6 mT. The comparison of S–H parameters of the EPR spectra of Mn 2+ ions in a new formed phase and in ZnO Wt indicates that the parameter A of the hyperfine structure in a new phase is slightly smaller and that the D parameter is more than two times lower than in ZnO Wt . The content of the newly formed phase (~1% to 2%) is significantly higher than the content of external impurity states in the initial ZnO sample. The observed EPR spectrum is attributed to the Mn 2+ ions in the zinc blende (sphalerite) ZnO phase (ZnO ZB ), created on the surface of ZnO wt nanoparticles during mechanical processing." @default.
- W917657308 created "2016-06-24" @default.
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- W917657308 date "2015-11-01" @default.
- W917657308 modified "2023-10-18" @default.
- W917657308 title "EPR detection of sphalerite ZnO in mechanically treated ZnO+0.1C nanosystem" @default.
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- W917657308 doi "https://doi.org/10.1016/j.mssp.2015.06.051" @default.
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