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- W9255159 abstract "The most important mechanisms which control the leaching process of (hazardous) elements from combustion residues are dissolution/precipitation and sorption processes. In this study these processes are discussed as far as the leaching of As and Se from coal fly ash is concerned. We have found that arsenate and selenite are the most important redox species in fly ash leachates. The leaching of As and Se from acidic fly ash is controlled by sorption on amorphous iron oxide and can be modelled using a simplified surface complexation model. The As and Se leaching from alkaline fly ash is probably controlled by sorption on a Ca-phase, possibly ettringite or portlandite. Arsenate is sorbed much less reversibly than selenite on different matrix minerals of fly ash (especially iron oxides). This property can explain the lower availability of As for leaching from fly ash." @default.
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- W9255159 date "1994-01-01" @default.
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- W9255159 title "Speciation of As and Se During Leaching of Fly Ash" @default.
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- W9255159 doi "https://doi.org/10.1016/s0166-1116(08)71479-1" @default.
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