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- W926216902 abstract "Abstract A major obstacle in realizing Na-ion batteries (NIBs) is the absence of suitable anode materials. Herein, we firstly report the anatase TiO 2 mesocages constructed by crystallographically oriented nanoparticle subunits as a high performance anode for NIBs. The mesocages with tunable microstructures, high surface area (204 m 2 g −1 ) and uniform mesoporous structure were firstly prepared by a general synthesis method under the assist of sodium dodecyl sulfate (SDS). It’s notable that the TiO 2 mesocages exhibit a large reversible capacity and good rate capability. A stable capacity of 93 mAhg −1 can be retained after 500 cycles at 10 C in the range of 0.01–2.5 V, indicating high rate performance and good cycling stability. This could be due to the uniform architecture of iso-oriented mesocage structure with few grain boundaries and nanoporous nature, allowing fast electron and ion transport and providing more active sites as well as freedom for volume change during Na-ion insertion. CV measurements demonstrate that the sodium-ion storage process of anatase mesocages is mainly controlled by pseudocapacitive behavior, which is different from the lithium-ion storage and further facilitates the high rate capability." @default.
- W926216902 created "2016-06-24" @default.
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- W926216902 date "2015-07-06" @default.
- W926216902 modified "2023-10-03" @default.
- W926216902 title "Iso-Oriented Anatase TiO2 Mesocages as a High Performance Anode Material for Sodium-Ion Storage" @default.
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- W926216902 doi "https://doi.org/10.1038/srep11960" @default.
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