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- W926303044 abstract "以2,4-二氯-6-辛氧基-1,3,5-三嗪为原料,经Kumada偶联及胺化两步反应合成了三嗪胺衍生物：4-（9-蒽基）-6-辛氧基-1,3,5-三嗪-2-胺（AOOTA）,总产率为38%.通过紫外-可见吸收光谱及荧光光谱研究了氯仿溶液中AOOTA在乙酸（HOAc）及三氟乙酸（TFA）作用下的光谱行为.研究发现AOOTA与HOAc在基态及激发态下均不能发生双氢键作用,而AOOTA与TFA相互作用基态下形成双氢键复合物,激发态下由于分子中蒽基及辛氧基与三嗪环间的C—C单键以及C—O单键的自由旋转,从而使得AOOTA与TFA分子间不能形成有效的氢键相互作用." @default.
- W926303044 created "2016-06-24" @default.
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- W926303044 date "2011-01-23" @default.
- W926303044 modified "2023-09-28" @default.
- W926303044 title "4-（9-蒽基）-6-辛氧基-1,3,5-三嗪-2-胺的合成及其在酸性介质中的光谱行为研究" @default.
- W926303044 doi "https://doi.org/10.7517/j.issn.1674-0475.2011.01.24" @default.
- W926303044 hasPublicationYear "2011" @default.
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