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- W92843346 abstract "Petroleum refining is the separation, and upgrading, of components of petroleum crude. In the upgrading of resid, now as in the early days of petroleum, characterization techniques are critical. Unlike with distillate fractions, for which routine analyses as gas chromatography (GC), mass spectrometry (MS), and liquid-phase nuclear magnetic resonance (NMR) are available, the resid fraction is not highly volatile nor necessarily fully soluble in typical organic solvents. Furthermore, the molecules in resid are large (molecular weights by vapor pressure osmometry ca. 300-1000), typically containing not only hydrogen and carbon but also nitrogen, sulfur,f and oxygen. To deal with this complex nature, there has been much comparison of resid to better defined, but much smaller, molecules. They will discuss issues relevant to this comparison, using reductive chemistry with potassium metal as a probe of both model compounds and resid. Their emphasis here will be on sulfur chemistry, and they discuss pertinent literature in the next section." @default.
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- W92843346 date "1987-04-01" @default.
- W92843346 modified "2023-09-23" @default.
- W92843346 title "Reductive alkylation of aromatic hydrocarbons: petroleum resid vs. model compounds" @default.
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