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- W93012775 abstract "The effects of solution temperature and molecular weight on the rheological responses of poly(vinyl alcohol) (PVA) semidilute solutions (13 g/dL- 19 g/dL) in dimethyl sulfoxide (DMSO) have been studied using PVA with two different number-average degrees of polymerization (P n ): 1700 and 4000. For the rheological experiments using dynamic shear, the PVA solution with a P n of 1700 showed rather simple Newtonian fluid behaviour, whereas that with P n of 4000 exhibited non-Newtonian shear thinning behaviour. Steady shear rheology experiments suggested that the lower P n PVA solutions were Newtonian fluids, which is consistent with the dynamic shear rheology results. However, an abrupt decrease of shear viscosity at high shear rates was observed for the higher P n PVA solutions at lower temperatures, such as 30 °C and 50 °C. At higher temperatures of 70 °C and 90 °C, the higher molecular weight PVA solutions exhibited simple shear thinning behaviour without any further complications of flow instability. The fact that temperature plays a critical role in controlling the observed flow instability of the PVA solutions in DMSO strongly suggests that there exist enhanced inter-chain interactions by hydrogen bonding of PVA chains beyond the chain entanglements, particularly for the higher P n PVA semidilute solutions at low temperatures. Therefore, it is important to consider both chain entanglements and hydrogen bonding interactions in order to process PVA solutions without causing undesirable flow instability." @default.
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- W93012775 date "2011-07-01" @default.
- W93012775 modified "2023-09-23" @default.
- W93012775 title "Flow Instability of Polyvinyl alcohol)/Dimethyl Sulfoxide Solution under Steady Shear" @default.
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- W93012775 doi "https://doi.org/10.1177/096739111101900602" @default.
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