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- W93142740 abstract "I describe the direct observation of H-bond exchange reaction within a water dimer isolated on a Cu(110) surface in this chapter. A water dimer consisted of H-bond donor and acceptor molecule can be produced by the association of water monomers. The STM image of a dimer is characterized by an incessant fluctuation between two states. Combined with DFT calculations it is found that the fluctuation corresponds to the H-bond donor–acceptor interchange where the role of each molecule is exchanged within a dimer. To elucidate the mechanism the interchange rate is investigated using the time-resolved measurement of STM. The voltage and current dependence of the rate unveil the interchange is not induced by STM, thus inherent in a dimer, at low bias voltages (V s < 40 mV). Furthermore, it is found that the rate of (H2O)2 is ~60 times larger than that of (D2O)2 in the low voltage region, indicating that the interchange process includes quantum tunneling. The voltage dependence also reveals the interchange rate is increased by the excitation of the intermolecular vibration mode of a dimer through the vibrationally assisted tunneling process." @default.
- W93142740 created "2016-06-24" @default.
- W93142740 creator A5064691163 @default.
- W93142740 date "2012-01-01" @default.
- W93142740 modified "2023-09-23" @default.
- W93142740 title "Water Dimer: Direct Observation of Hydrogen-Bond Exchange" @default.
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- W93142740 doi "https://doi.org/10.1007/978-4-431-54156-1_5" @default.
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