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- W935521787 abstract "Abstract Both 1,2:5,6-di- O -isopropylidene- and 1,2:5,6-di- O -cyclohexylidene-α- d -glucofuranose-derived ketones provided the corresponding branched 3- C -nitromethyl-congeners in the Henry reaction with nitromethane anion. Reduction of the nitro moiety followed by derivatization with iso(thio)cyanates gave 3- C -aminomethyl-hexofuranose-derived (thio)ureas. The relative configuration of the products in each series was unambiguously established by X-ray analysis. The title products were shown to act as organocatalysts in Friedel–Crafts alkylations of indoles with β-nitrostyrenes and in Michael additions of nitromethane to trans -chalcones." @default.
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- W935521787 date "2015-09-01" @default.
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- W935521787 title "Novel 3-C-aminomethyl-hexofuranose-derived thioureas and their testing in asymmetric catalysis" @default.
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- W935521787 doi "https://doi.org/10.1016/j.tetasy.2015.07.003" @default.
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