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- W939239868 abstract "We have investiagted the rotor-stator molecular crystalfullerene-cubane (C-60 center dot C8H8) by H-1 NMR spectroscopy in thetemperature range of 130 to 380 K. The H-1 line is broad and exhibitsfine structure characteristic of a multispin spectrum, indicating theabsence of angular reorientationos of the cubane molecule. Thetemperature and field dependence of the spin-lattice relaxation rate ofcubane protons is well explained in terms of field fluctuations arisingfrom reorientations of the C-60 molecules. Despite the closely packedstructure, the activation energy of these reorientations, 650 K isclose to that observed in the high-temperature phase of pure C-60indicating that the static cubane molecules act as efficient bearingfor the rotating fullerene molecules. (C) 2008 WILEY-VCH Verlag GmbH &Co. KGaA, Weinheim" @default.
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- W939239868 date "2008-01-01" @default.
- W939239868 modified "2023-09-27" @default.
- W939239868 title "H-1 NMR spectrum and spin-lattice relaxation in C-60 center dot C8H8" @default.
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