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- W942500610 abstract "Publisher Summary This chapter describes the alkaloids of calycanthaceae. The family Calycanthaceae is represented by only two genera, Calycanthus L., with about four species in the United States, and Chimonanthus Lindl. ( Meratia Loisel. ) with two Asiatic species. Its relation to other plant families is uncertain, and the nature of its chemical constituents has not shed any light on possible affinities. The belief in the presence of an indole nucleus in calycanthine was so firmly rooted that the first structures that bear some resemblance to the true one still retained the indole nucleus, even though they are largely based on the then-known structure of calycanine. There are few examples in the history of organic chemistry where deductions of structure based on identified fragments have been as wide of the mark as in the work on calycanthine. Reactions, that because of their mildness could be presumed to proceed without molecular rearrangements, yielded products that only served to confuse the real structure." @default.
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- W942500610 date "1965-01-01" @default.
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- W942500610 title "Chapter 16 The Alkaloids of Calycanthaceae" @default.
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- W942500610 doi "https://doi.org/10.1016/s1876-0813(08)60055-x" @default.
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