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- W94394886 abstract "Particles with radii 21–1010 nm, of methyl methacrylate homopolymer or copolymers with ethyl acrylate, were dispersed in high-boiling hydrocarbons. The stabilizer contained poly(12-hydroxystearic) acid. Viscosities at shear rates of 1–104 sec−1 were measured with cone and plate (Weissenberg rheogoniometer), becoming steady almost instantaneously. Severe shear thickening prevented continuing flow when the particle volume fraction exceeded about 47%. Shear thinning occurred at shear rates below 100 sec−1. Dispersions of one copolymer had lower viscosities than those of homopolymer. Blending two sizes of particles reduced the viscosity, so that the volume fraction of a homopolymer blend could be raised to 54% without severe shear thickening. The shear-thinning behavior at the lower concentrations is correctly represented by the Cross equation; analysis of the parameters in it suggests that two mechanisms operate, one possibility being partial collapse of the layer of stabilizer around each particle." @default.
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- W94394886 date "1977-03-01" @default.
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- W94394886 title "Shear thinning and thickening rheology" @default.
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- W94394886 doi "https://doi.org/10.1016/0021-9797(77)90338-1" @default.
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