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- W948141034 endingPage "232" @default.
- W948141034 startingPage "171" @default.
- W948141034 abstract "This chapter provides an overview of gallane and its derivatives. Monochlorogallane has indeed been the turning point in the hunt for gallane and its derivatives. It reacts in vacuo with lithium tetrahydrogallate at 243–250 K to give not only substantial quantities of elemental gallium and hydrogen but also gallane in yields up to 50%. The identity of the volatile, thermally perishable product has been established unequivocally by chemical analysis, by its vibrational and 1H NMR spectra, and by chemical trapping with trimethylamine to give the known molecular adduct (Me3N)2GaH3 as the sole product at 178 K. Efforts to improve the yield of gallane by using a solvent to give better control over the metathesis reaction have so far met with only limited success. The choice of medium is restricted by the need to minimize both the basic properties and the susceptibility to reduction of the would-be solvent. Thus, the mildly basic properties characterizing ether may enhance its ability to dissolve the reagents, but only at the expense of producing a sample of the gallane that can be freed from the solvent with difficulty." @default.
- W948141034 created "2016-06-24" @default.
- W948141034 creator A5064614811 @default.
- W948141034 creator A5079102484 @default.
- W948141034 date "1994-01-01" @default.
- W948141034 modified "2023-10-18" @default.
- W948141034 title "The Hunting of the Gallium Hydrides" @default.
- W948141034 cites W1521163473 @default.
- W948141034 cites W1557907834 @default.
- W948141034 cites W1591336065 @default.
- W948141034 cites W1949255766 @default.
- W948141034 cites W1967353835 @default.
- W948141034 cites W1967839727 @default.
- W948141034 cites W1971071134 @default.
- W948141034 cites W1973896637 @default.
- W948141034 cites W1976443125 @default.
- W948141034 cites W1976572013 @default.
- W948141034 cites W1984233027 @default.
- W948141034 cites W1984607437 @default.
- W948141034 cites W1985781813 @default.
- W948141034 cites W1985957164 @default.
- W948141034 cites W1986540572 @default.
- W948141034 cites W1987554480 @default.
- W948141034 cites W1989188849 @default.
- W948141034 cites W1990870123 @default.
- W948141034 cites W1991422811 @default.
- W948141034 cites W1991895109 @default.
- W948141034 cites W2000542535 @default.
- W948141034 cites W2001722532 @default.
- W948141034 cites W2002497240 @default.
- W948141034 cites W2003884030 @default.
- W948141034 cites W2007970946 @default.
- W948141034 cites W2012698533 @default.
- W948141034 cites W2015286940 @default.
- W948141034 cites W2018393640 @default.
- W948141034 cites W2021471918 @default.
- W948141034 cites W2022919333 @default.
- W948141034 cites W2023744250 @default.
- W948141034 cites W2025121512 @default.
- W948141034 cites W2026367688 @default.
- W948141034 cites W2029170648 @default.
- W948141034 cites W2030376825 @default.
- W948141034 cites W2033269406 @default.
- W948141034 cites W2033714396 @default.
- W948141034 cites W2039488101 @default.
- W948141034 cites W2039610102 @default.
- W948141034 cites W2041388873 @default.
- W948141034 cites W2041914472 @default.
- W948141034 cites W2042041528 @default.
- W948141034 cites W2042824272 @default.
- W948141034 cites W2042962723 @default.
- W948141034 cites W2043679012 @default.
- W948141034 cites W2044031208 @default.
- W948141034 cites W2046910705 @default.
- W948141034 cites W2047717967 @default.
- W948141034 cites W2050296771 @default.
- W948141034 cites W2050663832 @default.
- W948141034 cites W2052350191 @default.
- W948141034 cites W2054184367 @default.
- W948141034 cites W2054505931 @default.
- W948141034 cites W2054706133 @default.
- W948141034 cites W2055495620 @default.
- W948141034 cites W2055977895 @default.
- W948141034 cites W2056109480 @default.
- W948141034 cites W2060465835 @default.
- W948141034 cites W2060851937 @default.
- W948141034 cites W2061277730 @default.
- W948141034 cites W2061511534 @default.
- W948141034 cites W2063023527 @default.
- W948141034 cites W2065983086 @default.
- W948141034 cites W2066173886 @default.
- W948141034 cites W2069767723 @default.
- W948141034 cites W2070513934 @default.
- W948141034 cites W2074045045 @default.
- W948141034 cites W2075028212 @default.
- W948141034 cites W2076479867 @default.
- W948141034 cites W2076507964 @default.
- W948141034 cites W2077267279 @default.
- W948141034 cites W2079296457 @default.
- W948141034 cites W2079882415 @default.
- W948141034 cites W2080521678 @default.
- W948141034 cites W2084364067 @default.
- W948141034 cites W2084391127 @default.
- W948141034 cites W2087127871 @default.
- W948141034 cites W2092698056 @default.
- W948141034 cites W2093944553 @default.
- W948141034 cites W2099499700 @default.
- W948141034 cites W2107573244 @default.
- W948141034 cites W2111605053 @default.
- W948141034 cites W2115996120 @default.
- W948141034 cites W2116184915 @default.
- W948141034 cites W2120673998 @default.
- W948141034 cites W2126182462 @default.
- W948141034 cites W2158143516 @default.
- W948141034 cites W2315974075 @default.
- W948141034 cites W2317514837 @default.
- W948141034 cites W2321318494 @default.
- W948141034 cites W2324537474 @default.