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- W95261336 abstract "The zincosilicalites (MFI) with Si/Zn=100 have been prepared from, sodium silicate and sodium zincate. Various acids were used for reducing the alkalinity of the starting mixture (to the pH value of 11) in order to form the initial gel. The anions introduced with acids affected the crystallization as well as the properties of the resulting zincosilicates. The samples prepared with phosphates and sulfates showed the highest crystallinity, whereas the presence of HCl or acidic acid hindered forming a zeolite structure. The samples modified with various cations or with dispersed platinum showed a considerable catalytic activity in following reactions: propan-2-ol decomposition, cumene cracking, 1-butene isomerization, propan-2-ol oxidation, thiophene hydrodesulfurization. The samples synthesized in the presence of phosphates showed always the highest activity." @default.
- W95261336 created "2016-06-24" @default.
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- W95261336 date "2005-01-01" @default.
- W95261336 modified "2023-09-25" @default.
- W95261336 title "The influence of different anions on crystallization of MFI zincosilicates and their catalytic properties" @default.
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- W95261336 doi "https://doi.org/10.1016/s0167-2991(05)80341-6" @default.
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