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- W956475211 abstract "A zinc(Ⅱ)complex [Zn(bdc)(py)·H2O]π(bdc=1,4-benzenedicarboxylate,py=pyridine)has been prepared and characterized.Single crystal X-ray diffraction analysis reveals that the complex crystallizes in the monoclinic space group P21/n with a=0.84823(3),b=0.91440(3),c=1.65141(2)nm,β=91.243(2)°,V=1.28057(6)nm^3,Z=4.The corrdination geometry at each Zn(Ⅱ) center is a distorted tetrahedron.Two independent bdc ligands in a herringbone pattern link alternatively four-coordinated Zn(Ⅱ)centers into a one-dimensional poly meric chain.Hydrogen bonds among coordinated water molecules and uncoor dinated oxygen atoms of two independent bdc ligands form different polymeric chains extend one-dimensional polymeric chains into a three-dimensinal structre." @default.
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- W956475211 date "2002-01-01" @default.
- W956475211 modified "2023-09-23" @default.
- W956475211 title "Synthesis and crystal Structure of a Novel Hydrogen—Bonded Three—Dimensionnal Polymer [Zn(1,4—benzenedicarboxylate)—(pyridine·H2O]π" @default.
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