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• W957076919 endingPage "92" @default.
• W957076919 startingPage "86" @default.
• W957076919 abstract "Three new coordination polymers (CPs) of Zn(II)/Cd(II) have been synthesized using a dicarboxylate ligand, H2L = 5-(benzylamino)isophthalic acid, under hydro(solvo)thermal conditions. This ligand readily reacts with Zn(II) and Cd(II) metal salts to afford three CPs, {[Zn8(L)6(μ3-OH)4(H2O)6]·(DMF)·(H2O)2.5}n (1), [Zn(L)]n (2) and [Cd(L)(DMF)]n (3). All the complexes have been characterized by single crystal X-ray crystallography (XRD), IR spectroscopy, elemental analysis, thermogravimetry (TGA) and X-ray powder diffraction (PXRD). Single crystal X-ray studies reveal that 1–3 contain homometallic clusters, with SBUs varying from dimeric to tetrameric, depending upon the metal salts as well as the reaction conditions. Topologically, 1 represents an sql net, whereas 2 and 3 exhibits rare ptr and fes topological nets respectively. Luminescence studies were also carried for complexes 1–3, which exhibit emissions as a pair of bands upon excitation at 405 nm." @default.
• W957076919 created "2016-06-24" @default.
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• W957076919 date "2015-11-01" @default.
• W957076919 modified "2023-09-25" @default.
• W957076919 title "Zn(II)/Cd(II) based coordination polymers synthesized from a semi-flexible dicarboxylate ligand and their emission studies" @default.
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• W957076919 doi "https://doi.org/10.1016/j.poly.2015.07.056" @default.
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