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- W957361760 endingPage "155" @default.
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- W957361760 abstract "This chapter reviews the electronic structure of alkali metal adducts of aromatic hydrocarbons. Theories of chemical reduction are explained. The oldest theory of chemical reduction stems from Baeyer. The recent progress in the determination of the structure of alkaliaromatics is characterized by a close coordination between experimental investigations and quantum mechanical theory. The chapter discusses the electron affinities of conjugated hydrocarbons and the course of the chemical reduction. The recent advances in the understanding of the reaction of aromatic hydrocarbons with alkali metals have provided an explanation for many apparently unconnected experimental observations. A general approach to the course of chemical reduction, electrochemical reduction, and catalytic hydrogenation of hydrocarbons with conjugated double bonds has been given by Hoijtink. The reduction in inert solvents, reduction in proton-active solvents and properties of protonated anions are also covered. A brief discussion is provided on the characteristic features exhibited by the absorption spectra of alternant hydrocarbon molecules and their anions. The electron distribution in the anions is described. This chapter concludes with the discussion on the nature of alkali metal–hydrocarbon complexes in solution." @default.
- W957361760 created "2016-06-24" @default.
- W957361760 creator A5046480043 @default.
- W957361760 date "1965-01-01" @default.
- W957361760 modified "2023-10-16" @default.
- W957361760 title "Electronic Structure of Alkali Metal Adducts of Aromatic Hydrocarbons" @default.
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