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- W957503555 abstract "Selenophene (C4H4Se) is a five-membered heterocyclic compound containing one heteroatom. This chapter reviews advances in the chemistry of this heteroaromatic system. The chapter discusses the molecular structure and physicochemical properties of selenophene based on (1) microwave spectrum, (2) NMR spectra (3) IR and Raman spectra and (4) UV spectra. Selenophene or its homologs are obtained by two main methods—from other heterocycles by the Yur’ev or Perveev procedures, or by ring closure. Selenophene undergoes various electrophilic substitutions (nitration, sulfonation, halogenation, mercuration, chloromethylation, aminomethylation, acylaminomethylation, acylation, formylation, and hydrogen exchange) and other nuclear substitution reactions. The reactivity of selenophene compared with thiophene and furan based on substitutions at the nucleus; solvolysis of chloromethyl derivatives; and comparison between furan, thiophene, and selenophene from other properties and reactions is also described. Selenophenes are practically important as they can function as silicone oxidation inhibitors, complexing agents, and biologically active compounds." @default.
- W957503555 created "2016-06-24" @default.
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- W957503555 date "1970-01-01" @default.
- W957503555 modified "2023-09-26" @default.
- W957503555 title "Advances in Selenophene Chemistry" @default.
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- W957503555 doi "https://doi.org/10.1016/s0065-2725(08)60971-x" @default.
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