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- W957681475 abstract "In the title compound, [Pd(CH3)(C24H10F18NOP)(CH3CN)][SbF6]·0.5CH2Cl2, the PdII atom has a distorted square-planar environment being coordinated by an acetonitrile N atom [Pd—N = 2.079 (3) Å], a methyl C atom [Pd—C = 2.047 (4) Å] and the bidentate ligand 2-({[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}methyl)pyridine (L). In L, the short distance of 3.621 (3) Å between the centroids of pyridine and benzene rings indicates the presence of a π–π interaction. The crystal packing exhibits weak intermolecular C—H⋯F contacts. The solvent molecule has been treated as disordered between two positions of equal occupancy related by an inversion center." @default.
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- W957681475 date "2011-02-23" @default.
- W957681475 modified "2023-10-16" @default.
- W957681475 title "Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate" @default.
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- W957681475 doi "https://doi.org/10.1107/s1600536811005757" @default.
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