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- W957718465 abstract "This chapter discusses that the division of condensed matter into three states is readily understood if the interaction between two molecules is separated into short-ranged repulsive and long-ranged attractive parts. It is assumed that the sum of pair interactions is a good approximation to the total interaction energy in the dense matter. It discusses that high-quality fitting procedures to fit the pair theory to low density experimental data, also of high quality, removed the first obstacle for noble gas fluids, and modern computer simulation techniques removed the second. For other cases, theoretical calculations, adjusted to fit bulk fluid data or solid-state data, have provided a first approximation for the pseudopotentials of liquid metals and for the simpler intermolecular potentials. The chapter describes that the study of fluids covers both liquids and dense gases that form one continuous state of matter, because they are not separated by a phase boundary. By considering liquids and dense gases together, the discussion is over a wide range of state variables, pressure, volume, and temperature, and extends over regions where the relative importance of the repulsive and attractive parts of the interaction varies considerably." @default.
- W957718465 created "2016-06-24" @default.
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- W957718465 date "1987-01-01" @default.
- W957718465 modified "2023-10-10" @default.
- W957718465 title "14. Classical Fluids" @default.
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- W957718465 doi "https://doi.org/10.1016/s0076-695x(08)60574-8" @default.
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