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• W959091180 endingPage "10651" @default.
• W959091180 startingPage "10642" @default.
• W959091180 abstract "The morphology of liquid–liquid phase separated aerosols has a strong impact on their rate of gas and water uptake, and the type and rate of heterogeneous reactions in the atmosphere. However, it is extremely challenging to experimentally distinguish different morphologies (core–shell or partial wetting) of aerosols and to quantify the extent of wetting between the two phases. The aim of this work is to quantitatively predict the morphology of liquid–liquid aerosols from fundamental physical properties of the aerosol phases. We determine the equilibrium structure of liquid–liquid phase separated aerosols through free energy minimization and predict that the contact angle between the two liquids in the aerosol depends on the composition but not the amount of each phase. We demonstrate that for aerosols of diameter larger than ∼100 nm, the equilibrium contact angle can be accurately predicted from the surface tensions of each liquid with the vapor and between the two liquids through an expression that is identical to Young’s equation. The internal structure of smaller, ultrafine aerosols depends also on the value of the line tension between the two liquids and the vapor. The thermodynamic model accurately predicts the experimental morphology, core–shell or partial wetting, of all aerosols for which surface tensions are provided in the literature, and provides contact angles that cannot be accurately determined with state of the art experimental methods. We find that the contact angle of model atmospheric aerosols is rarely higher than 30°. We validate the thermodynamic predictions through molecular simulations of nonane–water droplets, and use the simulation data to compute line tension values that are in good agreement with theory and the analysis from experimental data in water–nonane droplets. Our finding of a simple analytical equation to compute the contact angle of liquid–liquid droplets should have broad application for the prediction of the morphology of two-phase atmospheric aerosols and its impact in their chemistry." @default.
• W959091180 created "2016-06-24" @default.
• W959091180 creator A5025247214 @default.
• W959091180 creator A5074139872 @default.
• W959091180 date "2015-08-13" @default.
• W959091180 modified "2023-10-05" @default.
• W959091180 title "Morphology of Liquid–Liquid Phase Separated Aerosols" @default.
• W959091180 cites W1787473029 @default.
• W959091180 cites W1882777343 @default.
• W959091180 cites W1963920118 @default.
• W959091180 cites W1964820623 @default.
• W959091180 cites W1967440516 @default.
• W959091180 cites W1968696455 @default.
• W959091180 cites W1973497554 @default.
• W959091180 cites W1975304033 @default.
• W959091180 cites W1976285915 @default.
• W959091180 cites W1978072737 @default.
• W959091180 cites W1978362851 @default.
• W959091180 cites W1978391752 @default.
• W959091180 cites W1981055837 @default.
• W959091180 cites W1983805127 @default.
• W959091180 cites W1993065427 @default.
• W959091180 cites W1993094858 @default.
• W959091180 cites W1993960392 @default.
• W959091180 cites W1998598381 @default.
• W959091180 cites W2000790153 @default.
• W959091180 cites W2004832076 @default.
• W959091180 cites W2004977767 @default.
• W959091180 cites W2008045014 @default.
• W959091180 cites W2009213223 @default.
• W959091180 cites W2012471594 @default.
• W959091180 cites W2012516290 @default.
• W959091180 cites W2014015109 @default.
• W959091180 cites W2017496924 @default.
• W959091180 cites W2018296170 @default.
• W959091180 cites W2018353195 @default.
• W959091180 cites W2019031737 @default.
• W959091180 cites W2019226349 @default.
• W959091180 cites W2019465613 @default.
• W959091180 cites W2025493871 @default.
• W959091180 cites W2025707787 @default.
• W959091180 cites W2028503574 @default.
• W959091180 cites W2030448810 @default.
• W959091180 cites W2031107710 @default.
• W959091180 cites W2031709116 @default.
• W959091180 cites W2037636973 @default.
• W959091180 cites W2039076302 @default.
• W959091180 cites W2041189078 @default.
• W959091180 cites W2042522215 @default.
• W959091180 cites W2044546397 @default.
• W959091180 cites W2044970877 @default.
• W959091180 cites W2047200483 @default.
• W959091180 cites W2047324399 @default.
• W959091180 cites W2048924026 @default.
• W959091180 cites W2049475242 @default.
• W959091180 cites W2051365363 @default.
• W959091180 cites W2055505005 @default.
• W959091180 cites W2055714082 @default.
• W959091180 cites W2059029179 @default.
• W959091180 cites W2059327711 @default.
• W959091180 cites W2060228139 @default.
• W959091180 cites W2062859605 @default.
• W959091180 cites W2063832287 @default.
• W959091180 cites W2065290028 @default.
• W959091180 cites W2065623307 @default.
• W959091180 cites W2066251384 @default.
• W959091180 cites W2068484606 @default.
• W959091180 cites W2069984356 @default.
• W959091180 cites W2070748753 @default.
• W959091180 cites W2070804679 @default.
• W959091180 cites W2071766040 @default.
• W959091180 cites W2075561153 @default.
• W959091180 cites W2076715136 @default.
• W959091180 cites W2088551608 @default.
• W959091180 cites W2091275940 @default.
• W959091180 cites W2092564698 @default.
• W959091180 cites W2093913153 @default.
• W959091180 cites W2094356860 @default.
• W959091180 cites W2095150688 @default.
• W959091180 cites W2099636727 @default.
• W959091180 cites W2100348914 @default.
• W959091180 cites W2101392489 @default.
• W959091180 cites W2102580742 @default.
• W959091180 cites W2105223773 @default.
• W959091180 cites W2112632155 @default.
• W959091180 cites W2112931561 @default.
• W959091180 cites W2113710294 @default.
• W959091180 cites W2121292063 @default.
• W959091180 cites W2123019220 @default.
• W959091180 cites W2124992912 @default.
• W959091180 cites W2125138077 @default.
• W959091180 cites W2125740784 @default.
• W959091180 cites W2126105726 @default.
• W959091180 cites W2133207065 @default.
• W959091180 cites W2134858944 @default.
• W959091180 cites W2137352412 @default.
• W959091180 cites W2139470170 @default.
• W959091180 cites W2150173477 @default.

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