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- W959485845 abstract "Publisher Summary This chapter discusses and focuses on spectral data, structural elucidation, synthesis, biosynthesis, and pharmacology of hasubanan alkaloids. On the basis of mass spectroscopic studies the cleavage patterns characteristic of hasubanan alkaloids are classified into four groups, the metaphanine type, the stephamiersine type, the oxostephasunoline type, and the hasubanonine type. Oxidation of aknadinine with silver nitrate gives a pair of dimeric compounds, one of which was identical to the naturally occurring bisaknadinine and the other assumed to be a stereoisomer arising from an axial chirality concerning the mode of biphenyl linkage. While, sodium borohydride reduction of aknadinine gives a pair of epimeric alcohols, one of which is found to be identical to natural epihernandolinol and the other identical to the known alkaloid hernandolinol. Some naturally occurring hasubanan alkaloids are submitted to screening for antitumor activity, but the results remain obscure." @default.
- W959485845 created "2016-06-24" @default.
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- W959485845 date "1988-01-01" @default.
- W959485845 modified "2023-09-24" @default.
- W959485845 title "Chapter 5 Hasubanan Alkaloids" @default.
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- W959485845 doi "https://doi.org/10.1016/s0099-9598(08)60300-4" @default.
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