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- W95977860 abstract "The cyclopropanation of unsaturated compounds, the generation of ylides in reaction with electron pair donors, intra- and intermolecular C-H insertion, and dimerization and polymerization are characteristic reactions of the electrophilic metal-carbene complexes formed during the decomposition of diazo compounds, catalyzed by transition-metal compounds. However, it remains unclear as to which of the two paths, i.e., the transformation of the palladium-vinylidenecyclopropane-methylene complex or the formation of bicyclopropylidene with subsequent isomerization of the palladium complex, forms the basis of the formation of the key intermediate. Therefore, for further study of the possibility of realizing this reaction on new model olefins and subsequent investigation of its mechanism, the authors investigated the reaction of bicyclopropylidene with diazomethane in the presence of palladium(II) acetate. Oligomethylenation, leading to the inclusion of three or four equivalents of methylene in the molecule, takes place during the reaction of bicyclopropylidene with diazomethane in the presence of palladium(II) acetate." @default.
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- W95977860 date "1989-01-10" @default.
- W95977860 modified "2023-09-28" @default.
- W95977860 title "Oligomethylenation of bicyclopropylidene by diazomethane in the presence of palladium(II) acetate" @default.
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