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- W959951605 abstract "This chapter focuses on some recent developments in the structural chemistry of organo-transition metal complexes. The growth in activity, over the last decade, in the general area of organometallic chemistry of transition metal ions is due, to a considerable extent, to the discovery and characterization of ferrocene. The oxidation state of the metal differs by +2 in the structures (I) and (11) but it must be recognized that this is simply a formalism and should not be interpreted literally any more than one understands the situation in ferrocene in which the iron is given an oxidation state of zero or +2 depending on whether the ligand is regarded as an anion or a radical. According to a molecular orbital theory of the electron distribution in a cyclic ligand, the possible role of structure (11) may be measured by the atom-electron localization energy. The formation of the exo-substituted ring may be assumed to be the result of the steric shielding of the inner side of the ring. Structural analyses have also been completed of the endo- and exo-ethoxy isomers of dimeric ethoxytetraphenylcyclobutenylpalladium chloride." @default.
- W959951605 created "2016-06-24" @default.
- W959951605 creator A5048358000 @default.
- W959951605 creator A5072599024 @default.
- W959951605 date "1967-01-01" @default.
- W959951605 modified "2023-10-14" @default.
- W959951605 title "The Structural Chemistry of Organo-Transition Metal Complexes: Some Recent Developments" @default.
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