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- W960484255 abstract "Publisher Summary This chapter describes the structural relationships within a group of quinones widely distributed in nature and the art of building up these and similar structures in the laboratory. As many of these procedures are readily adaptable for tracer syntheses, they allow the preparation of molecules labeled at different sites and with different isotopes, thus providing useful tools for biochemical and pharmacological research. The biochemically important vitamins K, the ubiquinones, plastoquinones, and tocoquinones, comprise a series of naphtho- and benzo-quinone derivatives bearing an unsaturated side chain of several isoprene units that are linked together head to tail. The biologically important compounds of the ubiquinone and plastoquinone series are synthesized according to the methods discussed in the chapter. In addition, the conversion of quinones—for example, phylloquinone and ubiquirione-6—into the corresponding chroineriols without affecting the unsaturated side chain can be smoothly performed in boiling pyridine or with sodium hydride." @default.
- W960484255 created "2016-06-24" @default.
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- W960484255 date "1967-01-01" @default.
- W960484255 modified "2023-09-25" @default.
- W960484255 title "Syntheses of Vitamins K and Related Compounds with Special Reference to Labeling" @default.
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- W960484255 doi "https://doi.org/10.1016/s0083-6729(08)60210-1" @default.
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